- When Kate has to 'babysit' Ducky and his mother at their house, when an ex-con (whom Ducky helped convict) starts killing off the key players in that conviction, Kate asks Gibbs what Ducky looked like when he was young. Gibbs pauses and answers "Illya Kuryakin".
- In another episode, Kate, Tony and Gibbs meet a fake colonel who is trying to prevent the team from investigating the deaths of two marines who were on undercover intelligence operations in South America. When they realise the colonel was an impostor, they try to tell Abby the details of what he looked like, so that she can make a composite photo on her computer. Kate and Tony disagree so much that Kate volunteers to do paperwork instead. She goes away and actually sketches the man they are looking for. Meanwhile, Gibbs and Abby continue with the attempt to do it on computer. By the time Kate returns, we hear Gibbs and Tony saying "Yeah, that looks like him!". We are surprised, thinking that they have made a picture of the villain. When the computer screen is turned around, it is a picture of Ducky, as a young Illya Kuryakin, and Gibbs is saying "Yeah, that's Ducky".
- When Gibbs retires, Ducky regards it as a betrayal of his duty. Ducky considers that Gibbs has quit. When Gibbs returns, he gets a frosty reception from Ducky: they indicate this by scrupulous politeness with each other and very formal modes of address. But eventually Ducky approaches Gibbs at the end of a long day that has brought back memories of old times. Ducky admits that there is something that he should have told Gibbs long ago, and that is "Welcome back". He holds out his hand to shake hands. Gibbs rises and comes around the desk, saying "You know how I feel about apologies", to which Ducky replies "They're a sign of weakness". And for once Gibbs says "Not between friends. I am sorry Ducky. I should have told you (about his dead wife and child)." and they shake hands which becomes a hug. And Gibbs whispers "Thank you". It is the closest we ever see Gibbs to social convention with a man. Which is indicative of how close the friendship between Ducky and Gibbs really is. One would go so far as to say they are probably best friends.
- When a Navy commander's head is found in the trunk/boot of a stolen car, Gibbs and Ducky unite in trying to find the rest of the man's body. When they have caught the bad guys, they realise that they have to choose between honouring a promise to the widow (to have the man's ashes returned in time for them to be scattered at sea from his last ship) or to keep the body for evidence, as they ought. Without having to speak, they agree to honour the promise to the widow and Ducky gleefully sneaks out with Gibbs to take the remains to the crematorium.
- When Ducky is tied down by a dastardly criminal who is going to embalm him alive, by exsanguinating him first, it is Gibbs who arrives in time and helps Ducky pull out the needle and holds him up. Ducky's response is "what took you so long", which merely causes Gibbs to chuckle at the ingratitude for arriving at all.
- Ducky's mother, Mrs Mallard, is even more of a character (eccentric) than Ducky. She is senile but chipper. She tells tales of her Donald as if he were still a young man and still hopes for grandchildren. She goes wandering and, when carers do not appear, Ducky has to bring her to work. Ducky is exasperated by her but also very fond of her. He regrets videotaping an episode of a TV show for her once, as she now watches that one episode every day.
- Ducky keeps corgis. He lives in a lovely house in the classic American style. It would suit Savannah Georgia in its graciousness.
- When Jen and Gibbs were partners in France, Jen allowed Gibbs to be arrested by the French police, but then helped him and Ducky escape by boat to England.
- Ducky knows, when he hears of Gibbs' wife and child death, that Gibbs has already killed the murderer. He knows Gibbs well enough to know that he would not let the killer live.
- Ducky keeps a special eye on Abby. He and she have mutual respect, but Ducky will not tolerate accusations of being wrong: he is too careful in his work. When there is a conflict of evidence, Ducky stands by his science.
- Ducky's Ditty on realizing “He’s never had the damned plague!” (re “Bury Your Dead” 5.01) (Tune: "I could have danced all night" from "My Fair Lady") This body’s lungs are fine (I think it so divine I want to dance and sing for joy) I rush upstairs to tell The team that Tony’s well (The dead man’s not our boy!) I really know I shouldn’t be excited When someone's life has been destroyed: I only know when he Proved to be plague-free I had to sing "he's no-o-o-o-ot our bo-o-o-o-o-o-o-o-oy!"
- In the early 1990s, a Dr. Donald Duck was practicing medicine on the Scottish mainland, just south of the Isle of Skye. The brass plate on his surgery was an unofficial tourist attraction in the town. Dr. Ducky Mallard is not as unlikely a name as it first sounds.
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